Single crystal structure feature of a new 0D Cr(III) complex, a catalyst for mild peroxidative oxidation of toluene

0565631 - FZÚ 2023 RIV NL eng J - Článek v odborném periodiku
Razmara, Z. - Correa, Cinthia Antunes
Single crystal structure feature of a new 0D Cr(III) complex, a catalyst for mild peroxidative oxidation of toluene.
Inorganic Chemistry Communications. Roč. 146, Dec (2022), č. článku 110117. ISSN 1387-7003. E-ISSN 1879-0259
Grant CEP: GA MŠMT(CZ) EF16_019/0000760
Grant ostatní: OP VVV - SOLID21(XE) CZ.02.1.01/0.0/0.0/16_019/0000760
Institucionální podpora: RVO:68378271
Klíčová slova: Cr(III) complexes * X-Ray structure * peroxidative oxidation * toluene * benzaldehyde
Obor OECD: Condensed matter physics (including formerly solid state physics, supercond.)
Impakt faktor: 3.8, rok: 2022
Způsob publikování: Omezený přístup
https://doi.org/10.1016/j.inoche.2022.110117

A novel water-soluble inorganic complex of Cr(III), formulated as [Cr(dipic)2,2′-bipyridine).H2O]2.4H2O 2(NO3) (complex 1) where dipic2- = pyridine 2,6-dicarboxylate was synthesized. Complex 1 has been characterized by elemental analysis, Fourier transformed-infrared (FT-IR) spectroscopy, thermogravimetric analysis (TGA), differential thermal analysis (DTA), and single-crystal X-Ray diffraction (SC-XRD). SC-XRD results revealed a triclinic system with space group P1 for the expected composition.
Trvalý link: https://hdl.handle.net/11104/0337147