Selective activation of aromatic C−H bonds catalyzed by single gold atoms at room temperature

0564414 - FZÚ 2023 RIV US eng J - Článek v odborném periodiku
Lowe, B. - Hellerstedt, J. - Matěj, Adam - Mutombo, Pingo - Kumar, D. - Ondráček, Martin - Jelínek, Pavel - Schiffrin, A.
Selective activation of aromatic C−H bonds catalyzed by single gold atoms at room temperature.
Journal of the American Chemical Society. Roč. 144, č. 46 (2022), s. 21389-21397. ISSN 0002-7863. E-ISSN 1520-5126
Grant CEP: GA ČR(CZ) GX20-13692X
Grant ostatní: AV ČR(CZ) AP1601
Program: Akademická prémie - Praemium Academiae
Institucionální podpora: RVO:68378271
Klíčová slova: nc-AFM * on surface chemistry * QM/MM * DFT
Obor OECD: Physical chemistry
Impakt faktor: 15, rok: 2022
Způsob publikování: Omezený přístup
https://doi.org/10.1021/jacs.2c10154

Here, we examine the interaction between 9,10-dicyanoanthracene (DCA) molecules and Au adatoms on an Ag(111) surface at room temperature (RT). Characterization via low-temperature scanning tunneling microscopy, spectroscopy, and non-contact atomic force microscopy, supported by theoretical calculations, revealed the formation of organometallic DCA-Au-DCA units, where C atoms at the ends of the anthracene moieties are bonded covalently to single Au atoms. The formation of this organometallic compound is initiated by a regioselective cleaving of C-H bonds at RT.
Trvalý link: https://hdl.handle.net/11104/0336086