Role of the magnetic anisotropy in atomic-spin sensing of 1D molecular chains

0564390 - FZÚ 2023 RIV US eng J - Článek v odborném periodiku
Wäckerlin, Christian - Cahlík, Aleš - Goikoetxea, J. - Stetsovych, Oleksandr - Medvedeva, Daria - López, Roso Redondo Jesús R. - Švec, Martin - Delley, B. - Ondráček, Martin - Pinar Solé, Andrés - Blanco-Rey, M. - Kolorenč, Jindřich - Arnau, A. - Jelínek, Pavel
Role of the magnetic anisotropy in atomic-spin sensing of 1D molecular chains.
ACS Nano. Roč. 16, č. 10 (2022), s. 16402-16413. ISSN 1936-0851. E-ISSN 1936-086X
Grant CEP: GA ČR(CZ) GX20-13692X; GA ČR(CZ) GA20-18741S; GA ČR(CZ) GA21-09766S; GA MŠMT LM2018110
Grant ostatní: AV ČR(CZ) AP1601
Program: Akademická prémie - Praemium Academiae
Institucionální podpora: RVO:68378271
Klíčová slova: D metal−organic nanomaterials * magnetism * scanning tunneling microscopy * nickelocene * inelastic tunneling spectroscopy * X-ray magnetic circular dichroism
Obor OECD: Condensed matter physics (including formerly solid state physics, supercond.)
Impakt faktor: 17.1, rok: 2022
Způsob publikování: Omezený přístup
https://doi.org/10.1021/acsnano.2c05609

Here, we provide a comprehensive study of the magnetic properties of metal–organic one-dimensional (1D) coordination polymers consisting of 2,5-diamino-1,4-benzoquinonediimine ligands coordinated with Co or Cr atoms synthesized under ultrahigh-vacuum conditions on a Au(111) surface. A combination of integral X-ray spectroscopy with local-probe inelastic electron tunneling spectroscopy corroborated by multiplet analysis, density functional theory, and inelastic electron tunneling simulations enables us to obtain essential information about their magnetic structures, including the spin magnitude and orientation at the magnetic atoms, as well as the magnetic anisotropy.
Trvalý link: https://hdl.handle.net/11104/0336146