Počet záznamů: 1
Hydrogenolysis of Carboxylic Ortho Esters
- 1.0561436 - ÚACH 2023 RIV US eng J - Článek v odborném periodiku
Kadyrov, Renat
Hydrogenolysis of Carboxylic Ortho Esters.
Journal of Organic Chemistry. Roč. 87, č. 19 (2022), s. 12673-12676. ISSN 0022-3263. E-ISSN 1520-6904
Institucionální podpora: RVO:61388980
Klíčová slova: Catalysts * Hydrogen * Hydrogenation * Organic compounds * Redox reactions
Obor OECD: Inorganic and nuclear chemistry
Impakt faktor: 3.6, rok: 2022
Způsob publikování: Omezený přístup
https://doi.org/10.1021/acs.joc.2c01116
It is demonstrated for the first time that carboxylic ortho esters may be reduced to acetals using hydrogen as the reducing agent. Hydrogenolysis was performed under mild conditions over commercially available hydrogenation catalysts (5% Pd/C and 5% Pt/C). The present method is especially useful for the selective transformation of carboxylic acids and lactones into acetals.
Trvalý link: https://hdl.handle.net/11104/0334931
Počet záznamů: 1