Azeotropic behavior of the 2-propanol + water+1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide system

0561253 - ÚCHP 2023 RIV NL eng J - Článek v odborném periodiku
Pavlíček, Jan - Bogdanić, Grozdana - Wichterle, Ivan
Azeotropic behavior of the 2-propanol + water+1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide system.
Fluid Phase Equilibria. Roč. 563, Dec 22 (2022), č. článku 113582. ISSN 0378-3812. E-ISSN 1879-0224
Grant CEP: GA ČR(CZ) GA20-06825S
Institucionální podpora: RVO:67985858
Klíčová slova: Correlation * ionic liquid * vapor -liquid equilibrium
Obor OECD: Physical chemistry
Impakt faktor: 2.6, rok: 2022
Způsob publikování: Open access s časovým embargem

Vapor-liquid equilibrium data were measured isothermally in the vicinity of azeotropic points of the title system at 333.15, 343.15, and 353.15 K. Data were processed using a newly-developed method based on relatively small amounts of input data, which provides thermodynamic description of azeotropic behavior. The regular two -parameter Redlich-Kister equation was used for this purpose. The parameters obtained were correlated with ionic liquid concentrations to express the smooth analytical dependence of both the azeotropic composition and pressure.
Trvalý link: https://hdl.handle.net/11104/0333942