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Spectroelectrochemistry of 1,10-phenantrolines Substituted by Pyrrolidine and Phenothiazine Redox-active Units
- 1.0557930 - ÚFCH JH 2024 RIV CZ eng C - Konferenční příspěvek (zahraniční konf.)
Sokolová, Romana - Wantulok, J. - Fiedler, Jan - Nycz, J. - Degano, I.
Spectroelectrochemistry of 1,10-phenantrolines Substituted by Pyrrolidine and Phenothiazine Redox-active Units.
41. Moderní elektrochemické metody. Sborník přednášek. Ústí nad Labem: Best servis, 2022 - (Navrátil, T.; Fojta, M.; Schwarzová, K.), s. 180-184. ISBN 978-80-905221-9-0.
[Moderní elektrochemické metody /41./. Jetřichovice (CZ), 22.05.2022-26.05.2022]
Institucionální podpora: RVO:61388955
Klíčová slova: 1,10-phenanthroline * Electrochemistry * Oxidation mechanism * Reduction mechanism
Obor OECD: Electrochemistry (dry cells, batteries, fuel cells, corrosion metals, electrolysis)
Compounds based on 1,10-phenanthroline (Phen) and their complexes are used in many fields, such as a stabilizing agent in the synthesis of nanoparticles, catalysts in homogeneous catalysis and as a semiconductor in organic light-emitting diodes (OLED) due to their coordination abilities. In this work, 1,10-phenanthrolines functionalized by pyrrolidine and phenothiazine units were studied by electrochemical methods. Cyclic voltammetry resulted in several oxidation and reduction voltammetric peaks. Structure-activity relationship was investigated using in situ spectroeletrochemistry, spectrophotometry, infrared spectroscopy and chromatography.
Trvalý link: http://hdl.handle.net/11104/0331821
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