Template synthesis, DNA binding, antimicrobial activity, Hirshfeld surface analysis, and 1D helical supramolecular structure of a novel binuclear copper(II) Schiff base complex

0557446 - FZÚ 2023 RIV GB eng J - Článek v odborném periodiku
Goudarziafshar, H. - Yousefi, S. - Tyula, Y.A. - Dušek, Michal - Eigner, Václav
Template synthesis, DNA binding, antimicrobial activity, Hirshfeld surface analysis, and 1D helical supramolecular structure of a novel binuclear copper(II) Schiff base complex.
RSC Advances. Roč. 12, č. 22 (2022), s. 13580-13592. E-ISSN 2046-2069
Grant CEP: GA ČR(CZ) GA14-03276S
Institucionální podpora: RVO:68378271
Klíčová slova: template synthesis * DNA binding * antimicrobial activity * Hirshfeld surface analysis * Schiff base complex * crystal structure
Obor OECD: Condensed matter physics (including formerly solid state physics, supercond.)
Impakt faktor: 3.9, rok: 2022
Způsob publikování: Open access

A new binuclear copper(II) Schiff base complex [Cu2 L2-(NO3)2].2CH3OH (1) [L = 2,6-bis((E)-(p-tolylimino)methyl)-4-methoxyphenol] was synthesized using a template method in which the tridentate N2O Schiff base ligand was derived from [1 + 2] condensation of 2,6-diformyl-4-methoxyphenol and p-methyl aniline in the presence of copper(II) ions as the template agent. The X-ray diffraction analyses revealed that this complex crystallizes in the monoclinic system with space group P21/n. The most remarkable structural feature of 1 is that it contains two types of 1D right-handed helical chains.
Trvalý link: http://hdl.handle.net/11104/0331923