Počet záznamů: 1
Nonaqueous capillary electrophoresis and quantum chemical calculations applied to investigation of acid-base and electromigration properties of azahelicenes
- 1.0555579 - ÚOCHB 2023 RIV DE eng J - Článek v odborném periodiku
Šolínová, Veronika - Štěpánová, Sille - Jančařík, Andrej - Klívar, Jiří - Šámal, Michal - Stará, Irena G. - Vacek Chocholoušová, Jana - Vacek, Jaroslav - Starý, Ivo - Kašička, Václav
Nonaqueous capillary electrophoresis and quantum chemical calculations applied to investigation of acid-base and electromigration properties of azahelicenes.
Electrophoresis. Roč. 43, 5/6 (2022), s. 696-707. ISSN 0173-0835. E-ISSN 1522-2683
Grant CEP: GA ČR(CZ) GA20-03899S; GA ČR(CZ) GA20-23566S
Institucionální podpora: RVO:61388963
Klíčová slova: acidity constant * azahelicenes * density functional theory * ionization constant * ionic mobility
Obor OECD: Organic chemistry
Impakt faktor: 2.9, rok: 2022
Způsob publikování: Omezený přístup
https://doi.org/10.1002/elps.202100331
Nonaqueous capillary electrophoresis (NACE) using methanol (MeOH) as a solvent of the BGEs and quantum mechanical density functional theory (DFT) have been applied to determine the thermodynamic acidity (ionization) constants (pKa) of mono- and diaza[5]helicenes, mono- and diaza[6]helicenes, and their dibenzo derivatives in MeOH and water.
Trvalý link: http://hdl.handle.net/11104/0330039
Počet záznamů: 1