Electrochemistry of Phospholes

0549322 - ÚFCH JH 2024 RIV CZ eng C - Konferenční příspěvek (zahraniční konf.)
Koláčná, Lucie - Liška, Alan - Ludvík, Jiří
Electrochemistry of Phospholes.
Sborník přednášek mezinárodní odborné konference XL. Moderní Elektrochemické Metody. Ústí nad Labem: Best Servis, 2021 - (Navrátil, T.; Fojta, M.; Schwarzová, K.), s. 126-129. ISBN 978-80-905221-8-3.
[Moderní Elektrochemické Metody /40./. Jetřichovice (CZ), 08.11.2021-12.11.2021]
Grant CEP: GA ČR(CZ) GA18-12150S
Institucionální podpora: RVO:61388955
Klíčová slova: Pentasubstituted phospholes * Electrochemistry * UV-vis spectra
Obor OECD: Electrochemistry (dry cells, batteries, fuel cells, corrosion metals, electrolysis)

Seventeen pentasubstituted phospholes with expected application in organic electronics were
synthesized and characterized electrochemically and by UV-vis spectra. Quantum chemical
calculations ofredox potentials and HOMO-LUMO energies were performed and experimental
and theoretical data were successfully correlated. Tuning of redox properties can be achieved
by combination of induction and resonance effects of substituents, extension / diminution of
the pi- delocalized system and by steric changes which affect intramolecular electron
communication.
Trvalý link: http://hdl.handle.net/11104/0325340