Ion Transfer Voltammetry across the Polarized Ionic Liquid/Water Interface: Base for Electrochemical Sensors

0549168 - ÚFCH JH 2024 RIV CZ eng C - Konferenční příspěvek (zahraniční konf.)
Langmaier, Jan - Samec, Zdeněk
Ion Transfer Voltammetry across the Polarized Ionic Liquid/Water Interface: Base for Electrochemical Sensors.
Sborník přednášek mezinárodní odborné konference XL. Moderní Elektrochemické Metody. Ústí nad Labem: Best Servis, 2021 - (Navrátil, T.; Fojta, M.; Schwarzová, K.), s. 143-146. ISBN 978-80-905221-8-3.
[Moderní Elektrochemické Metody /40./. Jetřichovice (CZ), 08.11.2021-12.11.2021]
Grant CEP: GA ČR(CZ) GA20-07350S
Institucionální podpora: RVO:61388955
Klíčová slova: ion transfer voltammetry * electrochemical detection * ionic liquid
Obor OECD: Electrochemistry (dry cells, batteries, fuel cells, corrosion metals, electrolysis)

Some electrochemical techniques such as voltammetry at the polarized interfaces between two
immiscible electrolyte solutions (ITIES) represent interesting alternatives to classical
electrochemistry. The benefit of the ion transfer voltammetry lies in the possibility of detection
of ionic species which are not otherwise redox active. The methodology enables apart of direct
determination of ionic samples (including pharmaceutical and clinical ones) also to monitor
reaction processes (acido-basic, enzymatic, etc.), determination of reaction substrates and
products in one experimental step, evaluation of reaction and transport kinetics, and estimation
of lipophilicity of involved species.
Trvalý link: http://hdl.handle.net/11104/0325180