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Ligand-dependent stereoselective Suzuki–Miyaura cross-coupling reactions of β-enamido triflates
- 1.0548519 - ÚOCHB 2022 RIV DE eng J - Článek v odborném periodiku
Chvojka, Tomáš - Markos, Athanasios - Voltrová, Svatava - Pohl, Radek - Beier, Petr
Ligand-dependent stereoselective Suzuki–Miyaura cross-coupling reactions of β-enamido triflates.
Beilstein Journal of Organic Chemistry. Roč. 17, Oct 29 (2021), s. 2657-2662. ISSN 1860-5397. E-ISSN 1860-5397
Grant CEP: GA MŠMT LTAUSA18037
Institucionální podpora: RVO:61388963
Klíčová slova: enamides * isomerization * Suzuki–Miyaura coupling * vinyl triflates
Obor OECD: Organic chemistry
Impakt faktor: 2.544, rok: 2021
Způsob publikování: Open access
https://doi.org/10.3762/bjoc.17.179
The stereoselective Suzuki–Miyaura cross-coupling of (Z)-β-enamido triflates is demonstrated. Depending on the nature of the ligand in the palladium catalyst, either retention or inversion of the configuration during the synthesis of β,β-diaryl-substituted enamides is observed. Thus, the method provides synthetic access to both isomers of the target enamides from (Z)-β-enamido triflates.
Trvalý link: http://hdl.handle.net/11104/0324565
Počet záznamů: 1