Stability of Different BTBP and BTPhen Extracting or Masking Compounds against γradiation

0547274 - ÚACH 2022 RIV US eng J - Článek v odborném periodiku
Distler, P. - Mindová, M. - Šebesta, J. - Grüner, Bohumír - Bavol, Dmytro - Egberink, H. - Verboom, W. - Babain, V.A. - John, J.
Stability of Different BTBP and BTPhen Extracting or Masking Compounds against γradiation.
ACS Omega. Roč. 6, č. 4 (2021), s. 26416-26427. ISSN 2470-1343. E-ISSN 2470-1343
GRANT EU: European Commission(XE) 755171 - GENIORS
Institucionální podpora: RVO:61388980
Klíčová slova: Absorption * Ligands * Solvents * Extraction * Irradiation
Obor OECD: Inorganic and nuclear chemistry
Impakt faktor: 4.132, rok: 2021
Způsob publikování: Open access

The radiolytic stability of hydrophobic extracting compounds CyMe4-BTBP and CyMe4-BTPhen and a hydrophilic masking agent (PhSO3H)2-BTPhen, widely employed for trivalent minor actinoid and lanthanoid separation, against γradiation was tested. Even though the solvent with a promising fluorinated diluent BK-1 provides better extraction properties compared to octan-1-ol, its radiation stability is much lower, and no extraction was observed already after an absorbed dose of 150 kGy (CyMe4-BTBP) or 200 kGy (CyMe4-BTPhen). For the (PhSO3H)2-BTPhen hydrophilic masking agent, the results showed that the rate of radiolytic degradation was significantly higher in 0.25 M HNO3 than in 0.5 M HNO3. For both the hydrophobic and hydrophilic agents, degradation was slower in the presence of both organic and aqueous phases during irradiation.
Trvalý link: http://hdl.handle.net/11104/0323549