Thermodynamic perturbation theory and equation of state developments.

0547145 - ÚCHP 2022 RIV UA eng J - Článek v odborném periodiku
Nezbeda, Ivo
Thermodynamic perturbation theory and equation of state developments.
Condensed Matter Physics. Roč. 24, č. 3 (2021), č. článku 30501. ISSN 1607-324X. E-ISSN 2224-9079
Grant CEP: GA ČR(CZ) GA20-06825S
Institucionální podpora: RVO:67985858
Klíčová slova: primitive model of water * SAFT equations of state * thermodynamic perturbation theory
Obor OECD: Physical chemistry
Impakt faktor: 0.750, rok: 2021
Způsob publikování: Open access
http://www.icmp.lviv.ua/journal/zbirnyk.107/33501/art33501.pdf

An alternative way of utilizing the thermodynamic perturbation theory of Wertheim for the development of equations of state for associating 2uid models is presented and detailed for water. The approach makes use of general features of the parameter of non-saturation to avoid the necessary solution of an algebraic equation and unbinds the results from a tight dependence on details of the simple reference 2uid model used in the perturbation theory.
Trvalý link: http://hdl.handle.net/11104/0323470