Influence of the ultrasonic-assisted synthesis on Al distribution in a MOR zeolite: from gel to resulting material

0546717 - ÚFCH JH 2022 RIV GB eng J - Článek v odborném periodiku
Olszówka, Joanna Elżbieta - Pashkova, Veronika - Kornas, Agnieszka - Dědeček, Jiří - Brus, Jiří - Urbanová, Martina - Tabor, Edyta - Klein, Petr - Brabec, Libor - Mlekodaj, Kinga
Influence of the ultrasonic-assisted synthesis on Al distribution in a MOR zeolite: from gel to resulting material.
New Journal of Chemistry. Roč. 45, č. 41 (2021), s. 19294-19303. ISSN 1144-0546. E-ISSN 1369-9261
Grant CEP: GA ČR(CZ) GJ17-09188Y; GA MŠMT(CZ) EF16_013/0001821
Grant ostatní: AV ČR(CZ) StrategieAV21/10
Program: StrategieAV
Institucionální podpora: RVO:61388955 ; RVO:61389013
Klíčová slova: solid-state nmr * co-beta zeolite * propene oligomerization * chabazite zeolites * reaction pathway * scr-nox * framework * aluminum * atoms * ions
Obor OECD: Physical chemistry; Polymer science (UMCH-V)
Impakt faktor: 3.925, rok: 2021
Způsob publikování: Omezený přístup

Two Al-rich mordenite samples were prepared by the same synthesis procedure except for the activation of the gel for which classical stirring and ultrasonic pretreatment was used. The organization of Al atoms both in the synthesis gel and zeolite product was investigated. Although both methods of the gel activation resulted in a similar transformation of Al and Si source according to NMR spectroscopy, stirring provided a significantly higher fraction of AlSiAl sequences in the gel compared to the ultrasonic pretreatment. These sequences were transferred to the zeolite product and were more populated in the conventionally prepared mordenite. Al atoms of AlSiAl sequences face different channels and mainly behave as single Al atoms, but they can also form Al pairs or close unpaired Al atoms, observed for the first time for mordenite.
Trvalý link: http://hdl.handle.net/11104/0323120