Mononuclear copper(I) Schiff base complex Cu((Cl-NO.sub.2./sub.-ba).sub.2./sub.en)I(CH.sub.3./sub.CN): Synthesis and crystal structure

0545360 - FZÚ 2022 RIV PK eng J - Článek v odborném periodiku
Khalaji, A.D. - Dušek, Michal - Eigner, Václav - Peyghoun, S.J.
Mononuclear copper(I) Schiff base complex Cu((Cl-NO₂-ba)₂en)I(CH₃CN): Synthesis and crystal structure.
Journal of the Chemical Society of Pakistan. Roč. 43, č. 1 (2021), s. 88-94. ISSN 0253-5106. E-ISSN 0253-5106
Grant CEP: GA MŠMT(CZ) LO1603; GA ČR(CZ) GA18-10504S
GRANT EU: European Commission(CZ) CZ.2.16/3.1.00/24510
Institucionální podpora: RVO:68378271
Klíčová slova: copper(I) complex * bidentate Schiff base * crystal structure * X-ray diffraction * copper(II) oxide * nanoparticles
Obor OECD: Condensed matter physics (including formerly solid state physics, supercond.)
Impakt faktor: 0.698, rok: 2021
Způsob publikování: Omezený přístup
https://jcsp.org.pk/issueDetail.aspx?aid=121515a3-b227-4429-8753-2cef7eac36e2

New mononuclear copper(I) Schiff base complex Cu((Cl-NO2-ba)2en)I(CH3CN) (1) containing a bidentate Schiff base ligand (Cl-NO2-ba)2en = 2,4-dichloro-5-nitro-benzylidene-1,2- diaminopropane, was prepared in an acetonitrile solution and characterized by elemental analyses (CHN), FT-IR and UV-Vis spectroscopy. Suitable dark-orange single crystals were obtained by slow evaporation of solvent at 5 ºC for several days. In addition, the title compound 1 was used as new precursor for the synthesis of copper(II) oxide nanoparticles via solid state thermal decomposition. The as prepared CuO product was characterized by FT-IR, XRD and SEM.
Trvalý link: http://hdl.handle.net/11104/0322069