Gothic-Arch Calcite from Speleothems of the Bohemian Karst (Czech Republic): Its Occurrence, Microscopic Ultrastructure and Possible Mechanism of Growth

0545192 - ÚJF 2022 RIV CH eng J - Článek v odborném periodiku
Suchý, Václav - Pachnerová Brabcová, Kateřina - Zachariáš, J. - Světlík, Ivo - Borecká, Lenka
Gothic-Arch Calcite from Speleothems of the Bohemian Karst (Czech Republic): Its Occurrence, Microscopic Ultrastructure and Possible Mechanism of Growth.
Minerals. Roč. 11, č. 8 (2021), č. článku 866. E-ISSN 2075-163X
Grant CEP: GA MŠMT EF16_019/0000728
Institucionální podpora: RVO:61389005 ; RVO:67985891
Klíčová slova: coralloids * fluid inclusions * radiocarbon * biocrystals * microbes * ribbon calcite * trigonal calcite * spiky calcite
Obor OECD: Mining and mineral processing; Mineralogy (USMH-B)
Impakt faktor: 2.818, rok: 2021
Způsob publikování: Open access
https://doi.org/10.3390/min11080866

Gothic arch calcite, a specific crystallographic variety of calcite known from some hot springs and tufa streams, has been newly recognized in the Koneprusy Caves. The gothic-arch calcite occurs on the exteriors of exotic coralloid speleothems where it coexists with scalenohedral (dogtooth) spar crystals. The crystals exhibit microscopic ultrastructural features including deeply eroded topography, etch pits, and spiky and ribbon calcite crystallites, pointing to its extensive natural etching. Many gothic-arch calcites originated as late-stage, secondary overgrowths on older, etched dogtooth calcite crystals. Its characteristic outward curvature resulted from the recrystallization of etching-liberated fine carbonate grains and newly formed needle-fiber calcite laths, which were accumulated and bound on the faces and at the bases of corroded crystals. These intimately coexisting destructive and constructive processes of carbonate crystal corrosion and growth were probably mediated by bacteria, fungi, or other microorganisms. Fluid inclusions embedded in calcite crystals point to a vadose setting and temperatures below similar to 50 degrees C. This, combined with the wider geological context, indicates that the gothic arch calcite crystals originated only during the late Pleistocene to Holocene epochs, when the cave, initially eroded by hypogene fluids in the deeper subsurface, was uplifted to the subaerial setting and exposed to the meteoric waters seeping from the topographic surface. The radiocarbon analysis shows that gothic-arch calcite crystals are generally older than similar to 55,000 years, but the surface layers of some crystals still reveal a weak C-14 activity, suggesting that microbiologically mediated alterations of the speleothems may have been occurring locally until now.
Trvalý link: http://hdl.handle.net/11104/0321928