A new lithium-rich zeolitic 10-MR zincolithosilicate MZS-1 hydrothermally synthesized under high pressure and characterized by 3D electron diffraction

0541703 - FZÚ 2022 RIV DE eng J - Článek v odborném periodiku
Steciuk, Gwladys - Schaf, O. - Tortet, L. - Pizzala, H. - Palatinus, Lukáš - Hornfeck, Wolfgang - Paillaud, J.L.
A new lithium-rich zeolitic 10-MR zincolithosilicate MZS-1 hydrothermally synthesized under high pressure and characterized by 3D electron diffraction.
European Journal of Inorganic Chemistry. Roč. 2021, č. 7 (2021), s. 628-638. ISSN 1434-1948. E-ISSN 1099-0682
Grant CEP: GA ČR GA19-08032S; GA MŠMT(CZ) LO1603
GRANT EU: European Commission(CZ) CZ.2.16/3.1.00/24510
Institucionální podpora: RVO:68378271
Klíčová slova: high pressure hydrothermal synthesis * lithium * superstructures * zeolites * zinc
Obor OECD: Condensed matter physics (including formerly solid state physics, supercond.)
Impakt faktor: 2.551, rok: 2021
Způsob publikování: Omezený přístup
https://doi.org/10.1002/ejic.202000939

We report the structure of a new high lithium content zincolithosilicate (MZS-1) obtained after hydrothermal treatment under high pressure from a glass precursor. After synthesis microcrystalline mixture of phases was obtained among which the main phase was unknown. Due to the sub micrometric size of the crystallites its structure was determined from precession-assisted 3D electron diffraction measured at 100 K and refined using the dynamical theory of diffraction. More accurate lattice parameters are obtained from Rietveld refinement of synchrotron powder data collected at the ambient temperature.
Trvalý link: http://hdl.handle.net/11104/0319233