Phosphinic acids as building units in materials chemistry

0540004 - ÚACH 2022 RIV NL eng J - Článek v odborném periodiku
Kloda, Matouš - Ondrušová, Soňa - Lang, Kamil - Demel, Jan
Phosphinic acids as building units in materials chemistry.
Coordination Chemistry Reviews. Roč. 433, APR (2021), č. článku 213748. ISSN 0010-8545. E-ISSN 1873-3840
Grant CEP: GA ČR(CZ) GA20-04408S
Grant ostatní: AV ČR(CZ) StrategieAV21/10
Program: StrategieAV
Institucionální podpora: RVO:61388980
Klíčová slova: Coordination polymer * Nanoparticle * Phosphinate * Sol-gel * Surface modification
Obor OECD: Inorganic and nuclear chemistry
Impakt faktor: 24.833, rok: 2021
Způsob publikování: Omezený přístup
https://doi.org/10.1016/j.ccr.2020.213748

Diaryl and dialkyl phosphinic acids are diverse groups of ligands capable of bonding to a wide variety of metal ions. This review provides a brief overview of their synthesis methods, and summarizes various functions and binding motifs phosphinic acids can have in the area of materials chemistry. The combination of these characteristics allows for many applications in coordination polymers, modification of surfaces, synthesis of nanoparticles, and sol–gel synthesis. The possibility of tuning electronic and steric properties by two aryl/alkyl substituents directly attached to phosphorus atom translates into unique properties of materials that cannot be replicated by the utilization of analogous phosphonates or carboxylates. Recent developments in the field and perspective directions of future research are also highlighted.
Trvalý link: http://hdl.handle.net/11104/0317687