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Controlling single molecule conductance by a locally induced chemical reaction on individual thiophene units
- 1.0539713 - FZÚ 2021 RIV DE eng J - Článek v odborném periodiku
Michnowicz, T. - Borca, B. - Petuya, R. - Schendel, V. - Pristl, M. - Pentegov, I. - Kraft, U. - Klauk, H. - Wahl, P. - Mutombo, Pingo - Jelínek, Pavel - Arnau, A. - Schlickum, U. - Kern, K.
Controlling single molecule conductance by a locally induced chemical reaction on individual thiophene units.
Angewandte Chemie - International Edition. Roč. 59, č. 15 (2020), s. 6207-6212. ISSN 1433-7851. E-ISSN 1521-3773
Grant CEP: GA MŠMT(CZ) EF16_019/0000760
Grant ostatní: OP VVV - SOLID21(XE) CZ.02.1.01/0.0/0.0/16_019/0000760
Institucionální podpora: RVO:68378271
Klíčová slova: DFT * single-molecule conductance * STM * AFM * strong anchoring
Obor OECD: Condensed matter physics (including formerly solid state physics, supercond.)
Impakt faktor: 15.336, rok: 2020
Způsob publikování: Open access
The parameters affecting the conductance are mainly related to their electronic structure and to the coupling to the metallic electrodes. Here, the experimental and theoretical analyses are focused on single tetracenothiophene molecules and demonstrate that an in‐situ‐induced direct desulfurization reaction of the thiophene moiety strongly improves the molecular anchoring by forming covalent bonds between molecular carbon and copper surface atoms. This bond formation leads to an increase of the conductance by about 50% compared to the initial state.
Trvalý link: http://hdl.handle.net/11104/0317425
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