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Poly[[tetradecakis(μ-propionato)heptabarium] propionic acid monosolvate tetrahydrate]
- 1.0537830 - FZÚ 2021 RIV GB eng J - Článek v odborném periodiku
Samoľová, Erika - Fábry, Jan
Poly[[tetradecakis(μ-propionato)heptabarium] propionic acid monosolvate tetrahydrate].
Acta Crystallographica Section E-Crystallographic Communications. Roč. 76, Feb (2020), s. 264-269. ISSN 2056-9890. E-ISSN 2056-9890
Grant CEP: GA MŠMT(CZ) LO1603
Institucionální podpora: RVO:68378271
Klíčová slova: crystal structure * hydrogen bonding * metal-organic compounds * positional disorder * occupational disorder
Obor OECD: Condensed matter physics (including formerly solid state physics, supercond.)
Způsob publikování: Open access
A relatively low number of structurally determined metal propionates with divalent cations are known so far. The title compound, {[Ba7(C3H5O2)14].0.946C3H6O2.4H2O}n, was prepared serendipitously. A few crystals of it were isolated from a batch of seemingly cubic crystals that grew from aqueous solutions of propionic acid. The title compound is represented by a metal–organic framework structure that is held together by Ba—O—Ba bonds, as well as by O—H ... O hydrogen bonds of moderate strength.
Trvalý link: http://hdl.handle.net/11104/0315664
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