Carboxylation Enhances Fragmentation of Furan upon Resonant Electron Attachment

0536327 - ÚFCH JH 2021 RIV US eng J - Článek v odborném periodiku
Zawadzki, Mateusz - Luxford, Thomas Frederick Murray - Kočišek, Jaroslav
Carboxylation Enhances Fragmentation of Furan upon Resonant Electron Attachment.
Journal of Physical Chemistry A. Roč. 124, č. 45 (2020), s. 9427-9435. ISSN 1089-5639. E-ISSN 1520-5215
Grant CEP: GA ČR(CZ) GA19-01159S
Institucionální podpora: RVO:61388955
Klíčová slova: Aromatic compounds * Carboxylation * Density functional theory
Obor OECD: Physical chemistry
Impakt faktor: 2.781, rok: 2020
Způsob publikování: Open access

We report a dissociative electron attachment study to 2-furoic acid (C5H4O3) isolated in a gas phase, which is a model molecule consisting of a carboxylic group and a furan ring. Dissociation of furan by low energy electrons is accessible only via electronic excited Feshbach resonances at energies of incident electrons above 5 eV. On the other hand, carboxylic acids are well-known to dissociate via attachment of electrons at subexcitation energies. Here we elucidate how the electron and proton transfer reactions induced by carboxylation influence stability of the furan ring. Overlap of the furan and carboxyl pi orbitals results in transformation of the nondissociative pi(2) resonance of the furan ring to a dissociative resonance. The interpretation of hydrogen transfer reactions is supported by experimental studies of 3-methyl-2-furoic and 5-methyl-2-furoic acids (C6H6O3) and density functional theory (DFT) calculations.
Trvalý link: http://hdl.handle.net/11104/0314111