On-surface synthesis of polyferrocenylene and its single-chain conformational and electrical transport properties

0535347 - FZÚ 2022 RIV DE eng J - Článek v odborném periodiku
Santhini, Vijai M. - Stetsovych, Oleksandr - Ondráček, Martin - Mendieta Moreno, Jesús Ignacio - Mutombo, Pingo - De La Torre Cerdeño, Bruno - Švec, Martin - Klívar, Jiří - Stará, Irena G. - Vázquez, Héctor - Starý, Ivo - Jelínek, Pavel
On-surface synthesis of polyferrocenylene and its single-chain conformational and electrical transport properties.
Advanced Functional Materials. Roč. 31, č. 5 (2021), č. článku 2006391. ISSN 1616-301X. E-ISSN 1616-3028
Grant CEP: GA MŠMT(CZ) EF16_019/0000760; GA MŠMT LM2015087; GA ČR(CZ) GA20-23566S; GA ČR(CZ) GA18-09914S
Grant ostatní: OP VVV - SOLID21(XE) CZ.02.1.01/0.0/0.0/16_019/0000760; AV ČR(CZ) AP1601
Program: Akademická prémie - Praemium Academiae
Výzkumná infrastruktura: e-INFRA CZ - 90140
Institucionální podpora: RVO:68378271 ; RVO:61388963
Klíčová slova: AFM simulation * charge transport * ferrocene * polyferrocenylene * scanning probe microscopy * spectroscopy
Obor OECD: Polymer science; Polymer science (UOCHB-X)
Impakt faktor: 19.924, rok: 2021
Způsob publikování: Omezený přístup
https://doi.org/10.1002/adfm.202006391

Metallopolymers contain multiple redox-active centers, which allow extra control of their intriguing properties. Ferrocene polymers are particularly attractive in this regard, but research of the iconic poly(1,1'-ferrocenylene), a main-chain ferrocene polymer with the most densely bound redox active iron centers, has practically stopped because it is an insoluble and rather inhomogeneous material. Herein, its synthesis on the Ag(111) surface is reported, based on the Ullmann coupling of 1',1-diiodo‐1,1‐biferrocene.
Trvalý link: http://hdl.handle.net/11104/0317421