Synthesis, characterization, and crystal structures of a thiosemicarbazone ligand and its silver(I) complex

0535342 - FZÚ 2021 RIV IR eng J - Článek v odborném periodiku
Khalaji, A.D. - Shahsavani, E. - Dušek, Michal - Kučeráková, Monika - Eigner, Václav
Synthesis, characterization, and crystal structures of a thiosemicarbazone ligand and its silver(I) complex.
Iranian Journal of Chemistry & Chemical Engineering-International English Edition. Roč. 39, č. 4 (2020), s. 23-28. ISSN 1021-9986. E-ISSN 1021-9986
Grant CEP: GA MŠMT(CZ) LO1603; GA ČR GA15-12719S
GRANT EU: European Commission(CZ) CZ.2.16/3.1.00/24510
Institucionální podpora: RVO:68378271
Klíčová slova: thiosemicarbazone * silver(I) complex * single crystal * triclinic structure * tetrahedral coordination
Obor OECD: Condensed matter physics (including formerly solid state physics, supercond.)
Impakt faktor: 0.759, rok: 2020
Způsob publikování: Open access

Thiosemicarbazone ligand 4Hbatsc = 4-hydroxybenzaldehyde-thiosemicarbazone and its silver(I) complex [Ag(PPh3)3(4Hbatsc)]NO3 were synthesized and characterized by elemental analysis (CHN), FT-IR spectroscopy, and single-crystal X-ray diffraction. Besides, the thermal behavior of the complex was studied using thermogravimetry in order to evaluate its thermal stability and thermal decomposition pathway. Finally, nanoparticles of the complex were prepared in an ultrasonic bath.

Trvalý link: http://hdl.handle.net/11104/0313391