Arc-related black shales as sedimentary archives of sea-level fluctuations and plate tectonics during the late Neoproterozoic. An example from the Bohemian Massif

0533896 - GLÚ 2021 RIV GB eng J - Článek v odborném periodiku
Ackerman, Lukáš - Pašava, J. - Žák, J. - Žák, Karel - Kachlík, V. - Šebek, O. - Trubač, J. - Svojtka, Martin - Veselovský, F. - Strnad, L. - Santolík, Václav
Arc-related black shales as sedimentary archives of sea-level fluctuations and plate tectonics during the late Neoproterozoic. An example from the Bohemian Massif.
Marine and Petroleum Geology. Roč. 123, January 2021 (2021), č. článku 104713. ISSN 0264-8172. E-ISSN 1873-4073
Grant CEP: GA ČR(CZ) GA17-15700S; GA ČR(CZ) GA20-13644S
Institucionální podpora: RVO:67985831
Klíčová slova: Molybdenum * Volcanic arc * Black shale * Neoproterozoic * Sea-level fluctuations * Silicification
Obor OECD: Geology
Impakt faktor: 5.361, rok: 2021
Způsob publikování: Omezený přístup
https://www.sciencedirect.com/science/article/pii/S0264817220304967

The late Neoproterozoic Lečice black shales and an overlying siliciclastic succession, Bohemian Massif, were deposited in a marine environment on a volcanic arc and provide insights into palaeoenvironmental conditions at the former active margin of northern Gondwana. Field relationships integrated with major/trace element and Mo–Cr–S isotope systematics in two different sections (Štěchovice and Břežany) indicate complex depositional settings intimately connected with the waning activity of the underlying volcanic arc. The Štěchovice black shales represent a deeper part of the basin and were first deposited in weakly anoxic conditions (lower stratigraphic level) with limited terrigenous supply, as reflected by their higher total organic carbon (TOC) and U contents and positive δ⁵³Cr, but negative δ³⁴Spyrite values accompanied by late-stage silicification by arc-related fluids. An abrupt change to oxygenated conditions and increased terrigenous flux, characterized by lower TOC, U and Mo and coupled, negative δ⁵³Cr and δ⁹⁸Mo, is documented in the upper level of the same section. By contrast, the Břežany black shales were deposited in a shallower part of the basin and their composition (e.g., low metal contents, negative δ⁵³Cr and δ⁹⁸Mo) suggests oxygenated conditions. Furthermore, the extensive syn-to post-depositional silicification by low-temperature hydrothermal fluids was associated with Si and Ba enrichment and elevated bacterial productivity leading to higher organic matter input. The black shale deposition was terminated by arc uplift, which supplied vast amounts of terrigenous material to the basin and produced a thick flysch sequence deposited at oxygenated conditions. The estimated age of the Lečice black shales (~580–560 Ma) suggests that their deposition may be linked to interactions between global eustatic sea level changes in response to the late Neoproterozoic glaciations (Gaskiers, Farquar) and dynamic arc topography.
Trvalý link: http://hdl.handle.net/11104/0314828