Chemical vapor generation of cadmium for analytical atomic spectrometry

0532385 - ÚIACH 2021 RIV CZ eng C - Konferenční příspěvek (zahraniční konf.)
Sagapova, Linda - Kodríková, Barbora - Svoboda, Milan - Musil, Stanislav - Kratzer, Jan
Chemical vapor generation of cadmium for analytical atomic spectrometry.
Proceedings of the 16th International Students Conference „Modern Analytical Chemistry”. Praha: Univerzita Karlova, 2020 - (Nesměrák, K.), s. 90-96. ISBN 978-80-7444-079-3.
[International Students Conference „Modern Analytical Chemistry” /16./. Praha (CZ), 17.09.2020-18.09.2020]
Grant CEP: GA ČR GA18-01116S
Institucionální podpora: RVO:68081715
Klíčová slova: cadmium * chemical vapor generation * atomic absorption spectrometry
Obor OECD: Analytical chemistry

Chemical vapor generation of cadmium volatile compounds was optimized, several reaction modifiers based on inorganic salts and complexes of CrIII+, CoII+, TiIII+, TiIV+ were tested. Their use resulted in 4-5 times enhancement in sensitivity, reflected also in corresponding increase of generation efficiency and better repeatability. Generation efficiency was determined from a comparison between sensitivities obtained with chemical vapor generation and conventional solution nebulization, both simultaneously coupled with inductively coupled plasma mass spectrometry. The identity of the generated cadmium compounds was identified.
Trvalý link: http://hdl.handle.net/11104/0310888