Počet záznamů: 1  

Resistivity and Thermal Expansion (4.2-820 K) of Skutterudites after Severe Plastic Deformation via HPT

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    0531633 - ÚFM 2021 RIV DE eng J - Článek v odborném periodiku
    Rogl, G. - Soprunyuk, V. - Schranz, W. - Zehetbauer, M.J. - Buršík, Jiří - Müller, H. - Bauer, E. - Rogl, P.F.
    Resistivity and Thermal Expansion (4.2-820 K) of Skutterudites after Severe Plastic Deformation via HPT.
    Zeitschrift für anorganische und allgemeine Chemie. Roč. 646, č. 14 (2020), s. 1267-1272. ISSN 0044-2313. E-ISSN 1521-3749
    Institucionální podpora: RVO:68081723
    Klíčová slova: Severe plastic deformation * Electrical resistivity * Thermal expansion * Thermoelectric skutterudites * Thermoelectrics
    Obor OECD: Physical chemistry
    Impakt faktor: 1.492, rok: 2020
    Způsob publikování: Omezený přístup
    https://onlinelibrary.wiley.com/doi/abs/10.1002/zaac.202000040

    Thermoelectric materials with a high figure of merit, ZT, are the essential basis to build thermoelectric generators, which can directly convert heat into electricity. Severe plastic deformation (SPD) via high-pressure torsion (HPT) was successfully applied to enhance ZT of ball-milled and hot-pressed skutterudites as well as to produce bulk nanostructured skutterudites directly from powders. SPD introduces many defects into the sample and in parallel the crystallite size is significantly reduced. During measurement-induced heating these defects anneal partially out, and the grains grow. In this work for the first time systematically the changes of the temperature-dependent electrical resistivity and of thermal expansion were compared. It could be shown that for p- and n-type skutterudites, being hot-pressed and HPT-processed as well as directly HPT-processed from compacted powder, these changes occur more or less simultaneously within the same temperature ranges. This evaluation gives a much deeper insight into the thermoelectric behavior of HPT samples under the influence of changing temperature.
    Trvalý link: http://hdl.handle.net/11104/0310258

     
     
Počet záznamů: 1  

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