Synthesis of Novel α,β-Unsaturated Sulfonic Acid Derivatives Containing Dithiocarbamate/Xanthate Groups by Ring Opening of an α,β-Unsaturated γ-Sultone

0525653 - ÚOCHB 2021 RIV DE eng J - Článek v odborném periodiku
Khalili Foumeshi, Maryam - Halimehjani, A. Z. - Beier, Petr
Synthesis of Novel α,β-Unsaturated Sulfonic Acid Derivatives Containing Dithiocarbamate/Xanthate Groups by Ring Opening of an α,β-Unsaturated γ-Sultone.
Synlett. Roč. 31, č. 10 (2020), s. 987-990. ISSN 0936-5214. E-ISSN 1437-2096
Institucionální podpora: RVO:61388963
Klíčová slova: dithiocarbamates * sultones * xanthates * sulfonic acids * nucleophilic substitution * propene sultone
Obor OECD: Organic chemistry
Impakt faktor: 2.454, rok: 2020
Způsob publikování: Omezený přístup
https://www.thieme-connect.de/products/ejournals/abstract/10.1055/s-0040-1707970

An efficient method is disclosed for the synthesis of novel α,β-unsaturated sulfonic acid derivatives containing dithiocarbamate/xanthate groups through ring opening of an α,β-unsaturated γ-sultone with dithiocarbamic acid salts or xanthates prepared in situ. Treatment of the primary products with hydrochloric acid afforded the corresponding β-chloro-γ-(dithiocarbamato)propanesulfonic acids in excellent yields.
Trvalý link: http://hdl.handle.net/11104/0309766