Non-covalent interactions of imidazolium-based ionic liquids with model pyrrolidones revealed by FTIR spectroscopy and quantum chemical model calculations

0524775 - ÚMCH 2021 RIV NL eng J - Článek v odborném periodiku
Kotov, Nikolay - Raus, Vladimír - Dybal, Jiří
Non-covalent interactions of imidazolium-based ionic liquids with model pyrrolidones revealed by FTIR spectroscopy and quantum chemical model calculations.
Journal of Molecular Liquids. Roč. 312, 15 August (2020), s. 1-14, č. článku 113445. ISSN 0167-7322. E-ISSN 1873-3166
Grant CEP: GA ČR(CZ) GA17-03810S
Institucionální podpora: RVO:61389013
Klíčová slova: ionic liquids * organic electrolyte solutions * non-covalent interactions
Obor OECD: Polymer science
Impakt faktor: 6.165, rok: 2020
Způsob publikování: Omezený přístup
https://www.sciencedirect.com/science/article/pii/S0167732220314021?via%3Dihub

Certain ionic liquids (ILs), such as 1-butyl-3-methylimidazolium chloride (bmimCl) and 1-ethyl-3-methylimidazolium acetate (emimAc), are potent cellulose solvents, but the high viscosity of the resulting solutions is problematic in many applications. Organic co-solvents are often employed to alleviate this problem. However, our understanding of the intermolecular interactions determining the IL/co-solvent mixture performance is very limited, hampering the further development of this class of cellulose solvents. Herein, we applied infrared spectroscopy (IR), Raman spectroscopy, and quantum chemical model calculations to investigate the intermolecular interactions in differently concentrated mixtures of bmimCl and emimAc with amidic co-solvents, N-methyl-2-pyrrolidone (NMP) and N-vinyl-2-pyrrolidone (NVP). Based on the detailed analysis of the vibrational spectra of individual mixture components and the improved assignment of the relevant characteristic bands, we determined that bmim+-co-solvent and emim+-co-solvent associates, stabilized by the hydrogen bonds between amidic carbonyl oxygens and the CH groups of the imidazolium rings, are formed in the mixtures. In addition, the data pointed to concomitant disruption of the H-bonds between the IL counterions as the co-solvent concentration was increased, which may indicate partial dissociation of the IL ion pairs. Further, through an extensive deconvolution analysis, we quantified the molar fractions of the co-solvent molecules involved in the associate formation, finding that this fraction is significantly lower for emimAc than for bmimCl mixtures at all the studied concentrations. On the other hand, the influence of the amidic co-solvent structure was negligible, suggesting that also other (aprotic) amides may be applicable as co-solvents. Furthermore, the calculated molar ratio of IL to interacting co-solvent molecules highlighted the possible differences in the associate stoichiometry. The findings indicate that the lower affinity of the IL to co-solvents in emimAc-based mixtures may lead to the retaining of larger IL-rich clusters and, consequently, the comparatively better performance of the system in cellulose dissolution. Finally, increased temperature was found to influence all the studied systems similarly, inflicting about 20% decrease in the fraction of interacting co-solvent molecules at 85 °C as compared to room temperature. In summary, the results of this study provide important implications for the design of new solvent systems for cellulose dissolution.
Trvalý link: http://hdl.handle.net/11104/0309145