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Comparison of prediction methods of heat capacity of ionic liquids with selected experimental data by means of advanced data analysis.

  1. 1.
    0524600 - ÚCHP 2021 RIV NL eng J - Článek v odborném periodiku
    Čanji, Maja - Bendová, Magdalena - Wagner, Zdeněk
    Comparison of prediction methods of heat capacity of ionic liquids with selected experimental data by means of advanced data analysis.
    Thermochimica Acta. Roč. 690, 20 AUG (2020), č. článku 178602. ISSN 0040-6031. E-ISSN 1872-762X
    Grant CEP: GA ČR(CZ) GA17-08218S
    Institucionální podpora: RVO:67985858
    Klíčová slova: ionic liquids * isobaric heat capacity * differential scanning calorimetry
    Obor OECD: Physical chemistry
    Impakt faktor: 3.115, rok: 2020
    Způsob publikování: Open access s časovým embargem

    Heat capacity of selected series of ionic liquids was predicted by means of several group contribution models of ionic liquid and compared with available experimental data. The examined series of ionic liquids were with methylimidazolium, menthoxymethyl imidazolium and ethoxyethoxyethyl imidazolium cations with different alkyl substituents, while the anions were the saccharinate or bistriflate. All data, experimental and predicted, were analyzed by means of mathematical gnostics and critically evaluated. Based on the thermodynamics of data and theory of measurement, mathematical gnostics is a novel non-statistical approach towards data uncertainty.
    Trvalý link: http://hdl.handle.net/11104/0310661

     
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