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Selected Electrochemical Properties of 4,4’-((1E,1’E)-((1,2,4-Thiadiazole-3,5-diyl)bis(azaneylylidene))bis(methaneylylidene))bis(N,N-di-p-tolylaniline) towards Perovskite Solar Cells with 14.4% Efficiency
- 1.0524583 - ÚFCH JH 2021 RIV CH eng J - Článek v odborném periodiku
Bogdanowicz, K.A. - Jewloszewicz, B. - Iwan, A. - Dysz, K. - Przybyl, W. - Januszko, A. - Marzec, M. - Cichy, K. - Świerczek, K. - Kavan, Ladislav - Zukalová, Markéta - Nadáždy, V. - Subair, R. - Majková, E. - Mičušík, M. - Omastová, M. - Özeren, M. D. - Kamarás, K. - Heo, D. Y. - Kim, S. Y.
Selected Electrochemical Properties of 4,4’-((1E,1’E)-((1,2,4-Thiadiazole-3,5-diyl)bis(azaneylylidene))bis(methaneylylidene))bis(N,N-di-p-tolylaniline) towards Perovskite Solar Cells with 14.4% Efficiency.
Materials. Roč. 13, č. 11 (2020), č. článku 2440. E-ISSN 1996-1944
Grant CEP: GA MŠMT(CZ) 8F17001
Institucionální podpora: RVO:61388955
Klíčová slova: imines * azomethines * electrochemical impendance spectroscopy
Obor OECD: Electrochemistry (dry cells, batteries, fuel cells, corrosion metals, electrolysis)
Impakt faktor: 3.623, rok: 2020
Způsob publikování: Open access
Planar perovskite solar cells were fabricated on F-doped SnO2 (FTO) coated glass substrates, with 4,4’-((1E,1’E)-((1,2,4-thiadiazole-3,5-diyl)bis(azaneylylidene))bis(methaneylylidene))bis(N,N-di-p-tolylaniline) (bTAThDaz) as hole transport material. This imine was synthesized in one step reaction, starting from commercially available and relatively inexpensive reagents. Electrochemical, optical, electrical, thermal and structural studies including thermal images and current-voltage measurements of the full solar cell devices characterize the imine in details. HOMO-LUMO of bTAThDaz were investigated by cyclic voltammetry (CV) and energy-resolved electrochemical impedance spectroscopy (ER-EIS) and were found at −5.19 eV and −2.52 eV (CV) and at −5.5 eV and −2.3 eV (ER-EIS). The imine exhibited 5% weight loss at 156 °C. The electrical behavior and photovoltaic performance of the perovskite solar cell was examined for FTO/TiO2/perovskite/bTAThDaz/Ag device architecture. Constructed devices exhibited good time and air stability together with quite small effect of hysteresis. The observed solar conversion efficiency was 14.4%.
Trvalý link: http://hdl.handle.net/11104/0308931
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