Počet záznamů: 1
Concentration-dependent impact of alkali Li metal doped mesoporous TiO.sub.2./sub. electron transport layer on the performance of CH.sub.3./sub.NH.sub.3./sub.PbI.sub.3./sub. perovskite solar cells
- 1.0520178 - FZÚ 2020 RIV US eng J - Článek v odborném periodiku
Amalathas, A.P. - Landová, Lucie - Conrad, B. - Holovský, Jakub
Concentration-dependent impact of alkali Li metal doped mesoporous TiO2 electron transport layer on the performance of CH3NH3PbI3 perovskite solar cells.
Journal of Physical Chemistry C. Roč. 123, č. 32 (2019), s. 19376-19384. ISSN 1932-7447. E-ISSN 1932-7455
Grant CEP: GA ČR GA18-24268S
Institucionální podpora: RVO:68378271
Klíčová slova: low-temperature * enhancing efficiency * halide perovskites * selective contact * rutile TiO2 * stability * hysteresis * interface * iodide
Obor OECD: Condensed matter physics (including formerly solid state physics, supercond.)
Impakt faktor: 4.189, rok: 2019
Způsob publikování: Omezený přístup
https://doi.org/10.1021/acs.jpcc.9b05355
TiO2 is commonly employed as an electron transport layer (ETL) in mesoscopic n−i−p perovskite solar cells (PSCs). However, the low electron mobility, low electrical conductivity, and high electronic trap states of TiO2 have negative impacts on further enhancement of PSC performance. Metal doping is an efficient way to improve the electronic properties of TiO2 films. In this work, we investigate the concentration-dependent impact of alkali lithium metal doping of the mesoporous TiO2 ETL on the performance of mesoscopic CH3NH3PbI3 PSCs. It was found that Li doping results in improvement in electrical conductivity and electron mobility and reduces the number of electronic trap states arising due to the oxygen vacancies within TiO2 lattice. The device performance relies on the concentration of Li doping, and the power conversion efficiency (PCE) of the PSC was improved from 13.64% to 17.59% for a Li doped mesoporous TiO2 layer with an optimized concentration of 30 mg/mL.
Trvalý link: http://hdl.handle.net/11104/0304867
Počet záznamů: 1