Versatile, one-pot introduction of nonahalogenated 2-ammonio-decaborate ions as boron cluster scaffolds into organic molecules, host-guest complexation with γ-cyclodextrin

0511495 - ÚACH 2020 RIV GB eng J - Článek v odborném periodiku
El Anwar, Suzan - Assaf, K. I. - Begaj, B. - Samsonov, M. A. - Růžičková, Z. - Holub, Josef - Bavol, Dmytro - Nau, W. M. - Gabel, D. - Grüner, Bohumír
Versatile, one-pot introduction of nonahalogenated 2-ammonio-decaborate ions as boron cluster scaffolds into organic molecules, host-guest complexation with γ-cyclodextrin.
Chemical Communications. Roč. 55, č. 91 (2019), s. 13669-13672. ISSN 1359-7345. E-ISSN 1364-548X
Grant CEP: GA ČR(CZ) GA19-04630S
Grant ostatní: AV ČR(CZ) DAAD-17-22
Program: Bilaterální spolupráce
Institucionální podpora: RVO:61388980
Klíčová slova: closo-decaborane anion * carboranes * coordinating anions
Obor OECD: Inorganic and nuclear chemistry
Impakt faktor: 5.996, rok: 2019
Způsob publikování: Omezený přístup
https://pubs.rsc.org/en/content/articlelanding/2019/CC/C9CC07678F#!divAbstract

We report the modification of the 2-ammonio group at halogenated decaborate ions with 2,3-epoxypropane, the product of which reacts readily with nucleophiles to form previously inaccessible coupling of polyhedra with organic molecules and materials. We demonstrate that these ions present a good binding motif in supramolecular chemistry.
Trvalý link: http://hdl.handle.net/11104/0301747


Vědecká data: CCDC, RSC publishing