Počet záznamů: 1
Photochemical C-H Amination of Ethers and Geminal Difunctionalization Reactions in One Pot
- 1.0508815 - ÚOCHB 2020 RIV DE eng J - Článek v odborném periodiku
Hernandez Guerra, Daniel - Hlavačková, Anna - Pramthaisong, Chiranan - Vespoli, Ilaria - Pohl, Radek - Slanina, Tomáš - Jahn, Ullrich
Photochemical C-H Amination of Ethers and Geminal Difunctionalization Reactions in One Pot.
Angewandte Chemie - International Edition. Roč. 58, č. 36 (2019), s. 12440-12445. ISSN 1433-7851. E-ISSN 1521-3773
Grant CEP: GA ČR(CZ) GA17-14510S
Grant ostatní: COST(XE) CM1201
Institucionální podpora: RVO:61388963
Klíčová slova: amination * C-H activation * photoreactions * radicals * sulfonyl azides
Obor OECD: Organic chemistry
Impakt faktor: 12.959, rok: 2019
Způsob publikování: Omezený přístup
https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201905209
A mild, atom-economic, and metal-free alpha-C-H amination of ethers using relatively stable nonafluorobutanesulfonyl (nonaflyl, Nf) azide as the aminating reagent to give N-sulfonyl hemiaminals is reported. This enables unprecedented C(sp(3)) difunctionalization reactions, leading to diverse functionalized amino group containing compounds starting from simple ethers in one pot.
Trvalý link: http://hdl.handle.net/11104/0299621
Počet záznamů: 1