Covalent diamond-graphite bonding: mechanism of catalytic transformation

0507874 - FZÚ 2020 RIV US eng J - Článek v odborném periodiku
Tulic, S. - Waitz, T. - Čaplovičová, M. - Habler, G. - Varga, Marián - Kotlár, M. - Vretenár, V. - Romanyuk, Olexandr - Kromka, Alexander - Rezek, Bohuslav - Skákalová, V.
Covalent diamond-graphite bonding: mechanism of catalytic transformation.
ACS Nano. Roč. 13, č. 4 (2019), s. 4621-4630. ISSN 1936-0851. E-ISSN 1936-086X
Grant CEP: GA ČR GF16-34856L
Institucionální podpora: RVO:68378271
Klíčová slova: diamond-to-graphite transformation * Ni-catalyzed graphitization * diamond-graphite covalent bonding * atomically resolved TEM * electrical conductance
Obor OECD: Condensed matter physics (including formerly solid state physics, supercond.)
Impakt faktor: 14.588, rok: 2019
Způsob publikování: Open access

Aberration-corrected transmission electron microscopy of the atomic structure of diamond−graphite interface after Ni-induced catalytic transformation reveals graphitic planes bound covalently to the diamond in the upright orientation. The covalent attachment, together with a significant volume expansion of graphite transformed from diamond, gives rise to uniaxial stress that is released through plastic deformation. We propose a comprehensive model explaining the Ni-mediated transformation of diamond to graphite and covalent bonding at the interface as well as the mechanism of relaxation of uniaxial stress. We also explain the mechanism of electrical transport through the graphitized surface of diamond. The result may thus provide a foundation for the catalytically driven formation of graphene−diamond nanodevices.
Trvalý link: http://hdl.handle.net/11104/0298830