Development of the poly(methylene blue) modified graphite electrodes for the electrochemical detection of hydrogen sulphide

0506992 - ÚFCH JH 2020 RIV CZ eng C - Konferenční příspěvek (zahraniční konf.)
Zlámalová, Magda - Janda, Pavel - Nesměrák, K.
Development of the poly(methylene blue) modified graphite electrodes for the electrochemical detection of hydrogen sulphide.
Proceedings of the 11th International Students Conference Modern Analytical Chemistry. Prague: Charles University of Prague, 2015 - (Nesměrák, K.), s. 232-236. ISBN 978-80-7444-036-6.
[International Students Conference on Modern Analytical Chemistry /11./. Prague (CZ), 22.09.2015-23.09.2015]
Institucionální podpora: RVO:61388955
Klíčová slova: methylene-blue * polymerization * polymers * cyclic voltammetry * electropolymerization
Obor OECD: Physical chemistry

A comparative study have been undertaken of the electropolymerization and electrochemical properties of deposited electroactive polymer on two different graphite electrode substrates: basal plane highly oriented pyrolytic graphite (HOPG) and pencil-graphite electrode (PGE). Poly(methylene blue) modified electrodes (HOPG/pMB and PGE/pMB) have been prepared by potential cycling in aqueous electrolyte solution containing methylene blue monomer. It has been found that electrochemical properties and electrocatalytic activity of deposited film are greatly influenced by the type of electrode substrate. Developed electrodes have been further investigated as potential sensors for hydrogen sulphide.
Trvalý link: http://hdl.handle.net/11104/0298104