Electrochemical Investigation of Different Boron Cluster Compounds in Water-based Electrolytes

0506411 - BFÚ 2020 RIV CZ eng C - Konferenční příspěvek (zahraniční konf.)
Fojt, Lukáš - Vespalec, Radim - Fojta, Miroslav - Grüner, Bohumír
Electrochemical Investigation of Different Boron Cluster Compounds in Water-based Electrolytes.
XXXVIII. Moderní elektrochemické metody. Sborník přednášek. Ústí nad Labem: Best Servis, 2018 - (Navrátil, T.; Fojta, M.; Schwarzová, K.), Č. 2018 (2018), s. 46-49. ISBN 978-80-905221-6-9.
[Moderní elektrochemické metody /38./. Jetřichovice (CZ), 21.05.2018-25.05.2018]
Grant CEP: GA ČR GBP206/12/G151
Institucionální podpora: RVO:68081707 ; RVO:61388980
Klíčová slova: boron cluster compounds * glassy carbon electrode * dpv * carboranes
Obor OECD: Physical chemistry; Inorganic and nuclear chemistry (UACH-T)

Boron cluster compounds (BCC) belongs to one or the proud sing compounds which ace used for medical treatment Their use for biochemical purposes is connected with use of water-based environments. Up to now, the BCC were predominantly characterized in non-aqueous milieus Therefore, we decided to undertake electrochemical research of BCC in water-based electrolytes. We have investigated several boron clusters with structures containing different number of vertexes (from 3 to 18), The structures were modified by endo- and exo- skeletal substituents. All used BCC were electrochemically active in broad potential region. which implies their possible use as biomarkers with tunable electrochemical response.
Trvalý link: http://hdl.handle.net/11104/0297653