Charge transfer between quasi-zero-dimensional nanostructures

0499434 - FZÚ 2019 RIV SK eng J - Článek v odborném periodiku
Král, Karel - Menšík, Miroslav
Charge transfer between quasi-zero-dimensional nanostructures.
Chemical Papers. Roč. 72, č. 7 (2018), s. 1697-1705. ISSN 0366-6352
Grant CEP: GA MŠMT(CZ) LTC17029; GA ČR GC16-10429J; GA ČR(CZ) GA15-05095S
Institucionální podpora: RVO:68378271 ; RVO:61389013
Klíčová slova: charge transfer * polymer * conductivity * low-dimensional nanostructures
Obor OECD: Condensed matter physics (including formerly solid state physics, supercond.); Condensed matter physics (including formerly solid state physics, supercond.) (UMCH-V)
Impakt faktor: 1.246, rok: 2018

In the present paper, we show the main features of the theoretical formula allowing us to understand the irreversible transfer of electrons or holes, as it may be observed in some electrically conducting (conjugated) polymers. The formula reported here is derived with the use of the nonequilibrium quantum transport theory. The key role in the formula is played by the electron-phonon interaction which is included in an approximation going beyond the limits of the finite order of the perturbation calculation. The transfer formula is developed for a simple model of the stacked conjugated polymer, which is represented here by two interacting quantum dots. The numerical calculations show the dependence of the charge carrier mobility on the charge carrier concentration and on the lattice temperature. A comparison with organic field-effect transistor experiments and with molecular-scale modeling on conjugated polymers is promising.
Trvalý link: http://hdl.handle.net/11104/0291637