A new supramolecular zinc(II) complex containing 4‐biphenylcarbaldehyde isonicotinoylhydrazone ligand: Nanostructure synthesis, catalytic activities and Hirshfeld surface analysis

0498160 - FZÚ 2019 RIV GB eng J - Článek v odborném periodiku
Tyula, Y.A. - Zabardasti, A. - Goudarziafshar, H. - Kučeráková, Monika - Dušek, Michal
A new supramolecular zinc(II) complex containing 4‐biphenylcarbaldehyde isonicotinoylhydrazone ligand: Nanostructure synthesis, catalytic activities and Hirshfeld surface analysis.
Applied Organometallic Chemistry. Roč. 32, č. 3 (2018), s. 1-15, č. článku e4141. ISSN 0268-2605. E-ISSN 1099-0739
Grant CEP: GA ČR(CZ) GA14-03276S
Institucionální podpora: RVO:68378271
Klíčová slova: catalytic activities * Hirshfeld surface analysis * hydrazone * sonochemical synthesis * sulfoxides
Obor OECD: Condensed matter physics (including formerly solid state physics, supercond.)
Impakt faktor: 3.259, rok: 2018

A new potentially tridentate hydrazone ligand, 4‐biphenylcarbaldehyde isonicotinoylhydrazone (4‐bpinh), was prepared by the condensation of biphenyl‐4‐carboxaldehyde with isonicotinic acid hydrazide. Then, its nano‐sized and single crystal of zinc complex were synthesized using sonochemical and heat gradient methods, respectively. The structure of complex, [Zn(4‐bpinh)2 Br2] (1), was determined by single‐crystal X‐ray diffraction, FT‐IR, and elemental analysis, and the nano‐structure of complex was characterized by FT‐IR, XRD, and SEM.
Trvalý link: http://hdl.handle.net/11104/0290690