Low-dimensional compounds containing cyanido groups. Part XXXV. Structure, spectral, thermal and magnetic properties of a binuclear Cu-II-biquinoline complex with bridging and terminal dicyanamide ligands

0497018 - FZÚ 2019 RIV US eng J - Článek v odborném periodiku
Potočňák, I. - Bukrynov, O. - Raczova, K. - Čižmár, E. - Vitushkina, S. - Váhovská, L. - Dušek, Michal - Štarha, P.
Low-dimensional compounds containing cyanido groups. Part XXXV. Structure, spectral, thermal and magnetic properties of a binuclear Cu-II-biquinoline complex with bridging and terminal dicyanamide ligands.
Acta Crystallographica Section C-Structural Chemistry. Roč. 74, č. 11 (2018), s. 1469-1476. ISSN 2053-2296. E-ISSN 2053-2296
Grant CEP: GA MŠMT(CZ) LO1603
GRANT EU: European Commission(CZ) CZ.2.16/3.1.00/24510
Institucionální podpora: RVO:68378271
Klíčová slova: dicyanamide * copper(II) 2,2 biquinoline * magnetic properties * crystal structure * thermal analysis
Obor OECD: Condensed matter physics (including formerly solid state physics, supercond.)
Impakt faktor: 0.930, rok: 2018

From the system CuCl2–biq–NaN(CN)2 (biq is 2,20-biquinoline), the binuclear molecular complex bis(μ-dicyanamido-κ2 N1:N5)bis[(2,20-biquinoline-κ2N,N´)(dicyanamido-κ N1)copper(II)], [Cu2(C2N3)4(C18H12N2)2] or [Cu2(biq)2(dca)2(μ1,5- dca)2] [dca is dicyanamide, N(CN)2_] was isolated and characterized by crystal structure analysis, and spectral, thermal and magnetic measurements. IR spectroscopy confirmed the presence of the biq and dca ligands.
Trvalý link: http://hdl.handle.net/11104/0289631