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B(C6F5)3 catalysis accelerates the hydrosilane chlorination by Ph3CCl

  1. 1.
    0492087 - ÚFCH JH 2019 GB eng J - Článek v odborném periodiku
    Šimarek, A. - Lamač, Martin - Horáček, Michal - Pinkas, Jiří
    B(C6F5)3 catalysis accelerates the hydrosilane chlorination by Ph3CCl.
    Applied Organometallic Chemistry. Roč. 32, č. 8 (2018), č. článku e4442. ISSN 0268-2605. E-ISSN 1099-0739
    Grant CEP: GA ČR(CZ) GA17-13778S
    Institucionální podpora: RVO:61388955
    Klíčová slova: hydrosilane chlorination * B(C6F5)3 catalysis * chlorosilanes
    Obor OECD: Physical chemistry
    Impakt faktor: 3.259, rok: 2018

    A chlorination of tertiary (5 examples), secondary (3 examples) and primary (PhSiH3) hydrosilanes by Ph3CCl with a catalytic amount of B(C6F5)3 is presented. The reaction was substantially faster than its non‐catalyzed version. The chlorination of secondary hydrosilanes and PhSiH3 proceeded in a stepwise manner, which allowed selective isolation of chlorohydrosilanes. The mechanism of catalytic hydrosilane chlorination seems to be distinct to mainstream B(C6F5)3 catalyzed reactions involving hydrosilanes (i.e. activation of Si‐H bond by the R3Si‐‐H‐‐B (C6F5)3 adduct formation). Contrary, the present process is based on an instant formation of [Ph3C]+[ClB(C6F5)3]− from B(C6F5)3 and Ph3CCl, followed by a hydride transfer from particular hydrosilane to tritylium cation with a concomitant generation of unstable
    silylium cation compensated by borate anion [ClB(C6F5)3]−. Subsequent decomposition of this ionic species leads to the corresponding chlorosilane and recuperation of B(C6F5)3.
    Trvalý link: http://hdl.handle.net/11104/0285649

     
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