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Various types of non-covalent interactions contributing towards crystal packing of halogenated diphospha-dicarbaborane with an open pentagonal belt
- 1.0491032 - ÚACH 2019 RIV GB eng J - Článek v odborném periodiku
Holub, Josef - Růžičková, Z. - Hobza, Pavel - Fanfrlík, Jindřich - Hnyk, Drahomír - Růžička, A.
Various types of non-covalent interactions contributing towards crystal packing of halogenated diphospha-dicarbaborane with an open pentagonal belt.
New Journal of Chemistry. Roč. 42, č. 13 (2018), s. 10481-10483. ISSN 1144-0546. E-ISSN 1369-9261
Grant CEP: GA ČR(CZ) GA17-08045S
Institucionální podpora: RVO:61388980 ; RVO:61388963
Klíčová slova: halogenated diphospha-dicarbaborane * bond
Obor OECD: Inorganic and nuclear chemistry; Physical chemistry (UOCHB-X)
Impakt faktor: 3.069, rok: 2018
We have prepared 3-Cl-10-I-nido-7,8,9,11-P2C2B7H7by the reaction of 3-Cl-nido-7,8,9,11-P2C2B7H8with I2in the presence of AlCl3. The product was obtained in a yield of 49% and was characterized by NMR spectroscopy and X-ray crystallography. Quantum chemical calculations have demonstrated that the crystal structure is stabilized by hydrogen, dihydrogen and pnictogen bonds.
Trvalý link: http://hdl.handle.net/11104/0285109
Vědecká data: RSC publishing
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