Reactivity of confined carboxylic acids in thin films

0490866 - ÚACH 2019 RIV US eng A - Abstrakt
Goronzy, D. P. - Avery, E. - Gallup, N. - Staněk, Jan - Macháček, Jan - Baše, Tomáš - Houk, K. - Weiss, P.
Reactivity of confined carboxylic acids in thin films.
Abstracts of papers - American Chemical Society. Roč. 255, MAR (2018), č. článku 686. ISSN 0065-7727.
[National Meeting and Exposition of the American-Chemical-Society (ACS) - Nexus of Food, Energy, and Water /255./. 18.03.2018-22.03.2018, New Orleans]
Institucionální podpora: RVO:61388980
Klíčová slova: carboxylic acids
Obor OECD: Inorganic and nuclear chemistry
https://tpa.acs.org/abstract/acsnm255-2874048/reactivity-of-confined-carboxylic-acids-in-thin-films

We examined SAMs composed of carborane cage molecules with a carboxylic acid functional group and tethered to a Au{111} surface via a thiol moiety. In previous work, using scanning tunneling microscopy (STM), the para-functionalized carboxylic acid carboranethiol was visualized in the form of mixed monolayers of functionalized and unfunctionalized molecules, with the functionalized molecule adopting the same nearest-neighbor spacing on the surface as the unfunctionalized para-carboranethiol, approximately 7.2 .
Trvalý link: http://hdl.handle.net/11104/0292714