Catalytic performance of advanced titanosilicate selective oxidation catalysts – a review

0488454 - ÚFCH JH 2019 RIV NL eng J - Článek v odborném periodiku
Přech, Jan
Catalytic performance of advanced titanosilicate selective oxidation catalysts – a review.
Catalysis Reviews-Science and Engineering. Roč. 60, č. 1 (2018), s. 71-131. ISSN 0161-4940. E-ISSN 1520-5703
Grant CEP: GA ČR GBP106/12/G015
Institucionální podpora: RVO:61388955
Klíčová slova: Epoxidation * hydrogen peroxide * selective oxidation * titanosilicate * zeolite
Obor OECD: Physical chemistry
Impakt faktor: 9.000, rok: 2018

This review article aims to cover the state-of-the-art of titanosilicate catalysts for selective oxidations developed within past seven years. Many elaboratedmaterials (e. g., layered and pillared titanosilicates, hierarchical composite materials, and others) have been prepared and thoroughly characterized. However, their catalytic properties have been usually investigated only using a single or few model substrates and compared with a benchmarking material. The main goal of this article is to summarize the novel catalysts and compare their catalytic performance with each other. The comparison is focused on epoxidation. In addition, phenol hydroxylation and sulphide oxidation are briefly covered.
Trvalý link: http://hdl.handle.net/11104/0283761