Copper, nickel and zinc complexes of a new water-soluble thiosemicarbazone ligand: Synthesis, characterization, stability and biological evaluation

0485481 - FZÚ 2018 RIV NL eng J - Článek v odborném periodiku
Hosseini-Yazdi, S.A. - Mirzaahmadi, A. - Khandar, A.A. - Mahdavi, M. - Rahimian, A. - Eigner, Václav - Dušek, Michal - Zarrini, G.
Copper, nickel and zinc complexes of a new water-soluble thiosemicarbazone ligand: Synthesis, characterization, stability and biological evaluation.
Journal of Molecular Liquids. Roč. 248, Dec (2017), s. 658-667. ISSN 0167-7322. E-ISSN 1873-3166
Grant CEP: GA ČR(CZ) GA15-12653S; GA MŠMT(CZ) LO1603
GRANT EU: European Commission(CZ) CZ.2.16/3.1.00/24510
Institucionální podpora: RVO:68378271
Klíčová slova: cytotoxicity * thiosemicarbazone * water-soluble Schiff base * stability * antioxidant * crystal structure
Obor OECD: Condensed matter physics (including formerly solid state physics, supercond.)
Impakt faktor: 4.513, rok: 2017

New water soluble Schiff base thiosemicarbazone ligand was obtained by the reaction of methylthiosemicarbazide with sulfonate salicylaldehyde and characterized by elemental analysis, spectroscopic methods and electrospray ionization mass spectrometry. The X-ray structure shows that sodium atoms are interconnected through sulfonate groups of the ligands into one-dimensional coordination polymer network. Reaction of the ligand with metal acetates produced following complexes: [Cu(HL)]2, NiHL and ZnHL. All complexes were characterized by means of elemental analysis, IR spectroscopy, and ESI-Mass measurements.
Trvalý link: http://hdl.handle.net/11104/0280495