Building Blocks Based on Halogenated closo-Borate Anions

0484848 - ÚACH 2018 RIV CN eng A - Abstrakt
Holub, Josef - Bakardjiev, Mario - Jelínek, T. - Fojt, Lukáš - Růžičková, Z. - Gabel, D. - Grüner, Bohumír
Building Blocks Based on Halogenated closo-Borate Anions.
IMEBORON 16 Programme. Hong Kong: Chinese University of Hong Kong, 2017. s. 169.
[IMEBORON: International Meeting on Boron Chemistry /16./. 09.07.2017-13.07.2017, Hong Kong]
Grant CEP: GA TA ČR(CZ) TH01020844
Institucionální podpora: RVO:61388980 ; RVO:68081707
Klíčová slova: closo-borate anions
Obor OECD: Inorganic and nuclear chemistry; Biophysics (BFU-R)

The chemistry of polyhalogenated polyhedral anions has received considerable attention due to possibility of easy halogenations with elemental halogens, the kinetic inertness of cageB-X (X= F, Cl, Br, I) bonds. Currently the whole area undergoes renaissance due to easy tuning of physicochemical properties (stability, polarity, lipophilicity, pKa, solubility, electrochemical potentials etc). Thus, the halogenated anions are considered for applications in electrochemistry as solid electrolytes, low nucleophilic anions or contrast materials and for radio-imaging in medicinal use.
Trvalý link: http://hdl.handle.net/11104/0279971