Thermodynamic properties of solubility of 2-methyl-5-arylfuran-3-carboxylic acids in organic solvents

0483885 - ÚMCH 2018 RIV UA eng J - Článek v odborném periodiku
Sobechko, I. - Dibrivnyi, V. - Horak, Y. - Velychkivska, Nadiia - Kochubei, V. - Obushak, M.
Thermodynamic properties of solubility of 2-methyl-5-arylfuran-3-carboxylic acids in organic solvents.
Chemistry and Chemical Technology. Roč. 11, č. 4 (2017), s. 397-404. ISSN 1996-4196
Institucionální podpora: RVO:61389013
Klíčová slova: enthalpy * entropy * Gibbs energy of solubility
Obor OECD: Polymer science

The temperature dependencies of both acids solubility in acetonitrile, dimethylketone, isopropanol, ethylacetate and benzene were investigated. The results were represented by Shredder’s equation according to which enthalpies, entropies and Gibbs energy of solubility at 298 K were determined. Fusion heats of the acids were determined using differential thermal analysis. In accordance with obtained values the enthalpies, entropies and Gibbs energy of mixing were calculated. The compensating effect of mixing was observed for al solvents with carboxy group.
Trvalý link: http://hdl.handle.net/11104/0279478