Silver makes better electrical contacts to thiol-terminated silanes than gold

0482376 - FZÚ 2018 RIV DE eng J - Článek v odborném periodiku
Li, H. - Su, T.A. - Camarasa-Gómez, M. - Hernangómez-Pérez, D. - Henn, S.E. - Pokorný, Vladislav - Caniglia, C.D. - Inkpen, M.S. - Korytár, R. - Steigerwald, M.L. - Nuckolls, C. - Evers, F. - Venkataraman, L.
Silver makes better electrical contacts to thiol-terminated silanes than gold.
Angewandte Chemie - International Edition. Roč. 56, č. 45 (2017), s. 14145-14148. ISSN 1433-7851. E-ISSN 1521-3773
Institucionální podpora: RVO:68378271
Klíčová slova: metal–molecule interactions * silanes * single-molecule electronics
Obor OECD: Condensed matter physics (including formerly solid state physics, supercond.)
Impakt faktor: 12.102, rok: 2017

We report that the single-molecule junction conductance of thiol-terminated silanes with Ag electrodes are higher than the conductance of those formed with Au electrodes. These results are in contrast to the trends in the metal work function Φ(Ag)<Φ(Au). As such, a better alignment of the Au Fermi level to the molecular orbital of silane that mediates charge transport would be expected. This conductance trend is reversed when we replace the thiols with amines, highlighting the impact of metal–S covalent and metal–NH2 dative bonds in controlling the molecular conductance. Density functional theory calculations elucidate the crucial role of the chemical linkers in determining the level alignment when molecules are attached to different metal contacts. We also demonstrate that conductance of thiol-terminated silanes with Pt electrodes is lower than the ones formed with Au and Ag electrodes, again in contrast to the trends in the metal work-functions.

Trvalý link: http://hdl.handle.net/11104/0277771