First organic–inorganic hybrid nanomaterial constructed from a Keggin-type polyoxometallate and a copper-dithiocarbamate complex: sonochemical synthesis, crystal structure and its adsorption performance for organic dye pollutants

0479316 - FZÚ 2018 RIV GB eng J - Článek v odborném periodiku
Farhadi, S. - Dušek, Michal - Siadatnasab, F. - Eigner, Václav - Mokhtari Andani, A.
First organic–inorganic hybrid nanomaterial constructed from a Keggin-type polyoxometallate and a copper-dithiocarbamate complex: sonochemical synthesis, crystal structure and its adsorption performance for organic dye pollutants.
Polyhedron. Roč. 126, Apr (2017), s. 227-238. ISSN 0277-5387. E-ISSN 1873-3719
Grant CEP: GA ČR(CZ) GA15-12653S; GA MŠMT LO1603
GRANT EU: European Commission(XE) CZ.2.16/3.1.00/24510
Institucionální podpora: RVO:68378271
Klíčová slova: organic–inorganic hybrid * polyoxometallate * dithiocarbamate * adsorption * organic dye pollutants
Obor OECD: Condensed matter physics (including formerly solid state physics, supercond.)
Impakt faktor: 2.067, rok: 2017

A novel organic–inorganic nanohybrid compound, namely [Cu{(HOCH2CH2)2NCS2}2]3[PW12O40](1), was prepared via the reaction of a copper(II) dithiocarbamate complex, Cu{(HOCH2CH2)2NCS2}2, and a Keggin-type heteropolyacid H3PW12O40. The nanohybrid 1 was characterized by FT-IR, UV–Vis, scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), the Brunauer–Emmett–Teller (BET) method, thermogravimetric analysis (TG), powder X-ray diffraction (XRD), elemental analyses and single-crystal X-ray diffraction.The structure of 1 consists of [PW12O40]3 building blocks and [Cu(HOCH2CH2)2NCS2)2]+ cationic moieties.

Trvalý link: http://hdl.handle.net/11104/0275557