Frustrated Lewis pairs-assisted reduction of carbonyl compounds

0470824 - ÚOCHB 2017 CZ eng C - Konferenční příspěvek (zahraniční konf.)
Marek, Aleš - Pedersen, M. H. F.
Frustrated Lewis pairs-assisted reduction of carbonyl compounds.
Proceedings of the 4th International Conference on Chemical Technology. Prague: Czech Society of Industrial Chemistry, 2016 - (Veselý, M.; Hrdlička, Z.; Hanika, J.; Lubojacký, J.), s. 534-538. ICCT. ISBN 978-80-86238-94-4. ISSN 2336-811X. E-ISSN 2336-8128.
[International Conference on Chemical Technology (ICCT) /4./. Mikulov (CZ), 25.04.2016-27.04.2016]
Institucionální podpora: RVO:61388963
Klíčová slova: carbonyl compounds * frustrated Lewis parts * alcohol synthesis
Kód oboru RIV: CC - Organická chemie

An alternative and robust method for the reduction of carbonyl groups by frustrated Lewis pairs (FLPs) is reported in this paper. With its very mild reaction conditions, good to excellent yields, absolute regioselectivity and the non-metallic character of the reagent, it provides an excellent tool for 1H, 2H as well as 3H chemistry. It is a new strategy for the one-pot synthesis of aromatic alcohols selectively labeled with heavy isotopes of hydrogen.
Trvalý link: http://hdl.handle.net/11104/0268449