Recent progress in the development of halogenated building blocks based on closo-decaborate and closo-dodecaborate anions

0469486 - ÚACH 2018 RIV RU eng A - Abstrakt
Holub, Josef - Bakardjiev, Mario - Jelínek, T. - Růžičková, Z. - Gabel, D. - Grüner, Bohumír
Recent progress in the development of halogenated building blocks based on closo-decaborate and closo-dodecaborate anions.
EuroBoron 7 : Book of Abstracts. Moscow: Federal Agency for Scientific Organisations, 2016. s. 109.
[European Conference on Boron Chemistry /7./. 04.09.2016-08.09.2016, Suzdal]
Grant CEP: GA TA ČR(CZ) TH01020844
Institucionální podpora: RVO:61388980
Klíčová slova: closo-dodecaborate anions
Obor OECD: Inorganic and nuclear chemistry
https://drive.google.com/file/d/0B_HxRmKDUQ2tUnNDRUc3bldiVkE/view

In this contribution we report on procedures that facilitate easy perhalogenation of basic 10-and12-vertex borane anion. New preparative methods for perhalogenation of the [B10H10]2- ion that produce [B10H10]2- species (X=Cl, Br,I) have been developed starting from old original procedures.
Trvalý link: http://hdl.handle.net/11104/0267269